Influence of Bonding and Polarization to Nephelauxetic Effect 成键和极化对电子云扩大效应的影响
Calculation of Nephelauxetic Effect of Ni~ ( 2+) and Er~ ( 3+) Ions in Solids Ni~(2+)和Er~(3+)在固体中的电子云扩大效应计算
The nephelauxetic effects of Ni2+ and Er3+ in solids were systematically calculated by means of a new method based on the dielectric description theory of chemical bond on complex crystals. 应用介电描述的复杂晶体化学键理论,给出计算Ni2+和Er3+在固体中的电子云扩大效应的新方法。
The radial wave function R_ ( 3d)( r) of Fe~ ( 3+) ion has been obtained semi-empirically. The nephelauxetic effects of Fe~ ( 3+) ions have been explained. 本文半经验地得到了Fe~(3+)自由离子及其络离子系统的径向波函数R3d(r),解释了3d电子的电子云延伸效应。