Hydroformylation of higher olefins is a very important process in the field of petrochemical industry. 高碳烯烃氢甲酰化是最重要的石化技术之一。
Advance in Hydroformylation of Olefin Catalyzed by Metal-N-Heterocyclic Carbene Complexes 金属-N-杂环卡宾配合物催化氢甲酰化反应的研究进展
Effect of Impurities in Ionic Liquid on 1-Hexene Hydroformylation 离子液体中杂质对1-己烯氢甲酰化反应的影响
Progress of Rhodium/ Diphosphine-Catalyzed Homogeneous Hydroformylation of Internal Olefins 铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展
The production technologies of1,3-propanediol by hydroformylation of ethylene oxide, hydration and hydrogenation of acrolein, and corn fermentation are summarized from their material, catalyst system, process, development and production status. 综述了环氧乙烷羰基化法、丙烯醛水合加氢法和微生物发酵法生产1,3-丙二醇工艺路线的原料、催化体系、工艺过程及研发状况。
Recent development in hydroformylation of ethene to propanal by catalytic synthesis is introduced in this paper. 本文综述了采用均相催化剂、均相固载化催化剂以及多相催化剂催化合成丙醛的研究成果。
Recent advances in hydroformylation of olefin catalyzed by metal-N-heterocyclic carbene ( NHC) complexes especially Rh-NHC complex were reviewed on with an intention to promote relevant research. N-杂环卡宾金属配合物的研究在近几年来得到迅速的发展,总结了酮硅氢加成反应中N-杂环卡宾金属配合物催化剂的应用新进展。
Aqueous Phosphine-Rh Complexes Supported on Nano-SiO_2 for Olefin Hydroformylation; Preparation and Characterization of Polyaniline in Soluble Polymeric Solution 纳米硅胶负载型水溶性铑膦络合物烯烃氢甲酰化催化性能的研究水溶性聚合物溶液中聚苯胺的合成与表征
Catalysts for olefin hydroformylation include Co-base catalysts and Rh-base catalysts mainly. 烯烃氢甲酰化反应用催化剂主要包括钴基催化剂和铑基催化剂。
Research for Hydroformylation of Ethylene in FCC Off-gas to Propanal Over PPh_3-Rh/ SiO_2 Catalysts PPh3-Rh/SiO2催化剂上干气中的乙烯氢甲酰化制丙醛研究
We studied the hydroformylation of 1-octene catalyzed by OPGPP/ Rh ( acac)( CO) 2 complex. 作者重点考察了OPGPP/Rh(acac)(CO)2配合物催化剂对1-辛烯氢甲酰化反应及OPGPP/Ru3(CO)(12)配合物催化剂对烯烃加氢反应的催化活性。
Hydroformylation of High Olefin& Influence of Electronic and Steric Effects of Phosphine Ligand 长链烯烃氢甲酰化反应研究&膦配体的电子效应和空间效应影响
This paper studied the catalytic performances of water-soluble phosphine-rhodium complexes in room temperature ionic liquids for 1-hexene hydroformylation. 研究了水溶性膦配体铑配合物在若干离子液体中的1己烯氢甲酰化反应性能。
A series of hydroformylation catalysts were prepared by supporting Rhodium complex in the supporters modified by phosphotungstic acid. 将铑络合物担载于磷钨酸改性的载体上制备了一系列新型催化剂。
Structure and activity of the low pressure hydroformylation COBALT-PHOSPHINE catalyst system 低压醛化钴-膦系催化剂结构和性能的研究
The phase behavior of the hydroformylation of propylene in supercritical CO_ 2 was simulated. 模拟了超临界丙烯氢甲酰反应体系的相行为。
Hydroformylation of High Olefin in Two-phase Catalytic System-Influence of Phosphines on the Activity and Selectivity 两相体系中长链烯烃氢甲酰化反应研究&膦配体对活性和选择性的影响
Study on modified iridium complexes as catalysts in hydroformylation of styrene 苯乙烯氢甲酰化反应铱基催化剂的改性研究
Progresses in the research and development on two-phase ( water-organic) hydroformylation of olefins 两相(水-有机)烯烃氢甲酰化研究与开发进展
Study on Catalyst and Process for Preparing 1,3-PDO by Hydroformylation 羰基合成1,3-PDO催化剂和工艺研究
Biphasic Asymmetric Hydroformylation and Hydrogenation in Ionic Liquids 基于离子液体的两相不对称氢甲酰化和加氢催化反应
The studies on the hydroformylation of higher olefins over rhodium-phosphine catalysts in the past decade were reviewed. In this paper, we introduced the process in Mitsubishi Kasei over TPPO/ Rh and the developments in biphasic catalysis in this field, especially the water-organic two-phase catalysis. 介绍了近年来铑/膦催化高碳烯烃氢甲酰化的研究和开发进展,特别是以TPPO/Rh为催化剂的MitsubishiKasei工艺和水/有机两相体系为主的各种两相催化技术。
Numerous applications of two phase catalysis to hydroformylation, hydrogenation and other organic reactions are also described. 两相催化在烯烃的氢甲酰化反应、不饱和化合物的加氢反应以及其它有机反应中获得了广泛的应用。
Synthesis of new chiral phosphine ligands and their applications in the asymmetric hydroformylation of styrene 新的手性膦配体的合成及其在苯乙烯不对称氢甲酰化反应中的应用
The use different rhodium complexes as hydroformylation catalysts for butene is studied. 制备了一系列铑配合物,并对其催化丁烯氢甲酰化的催化性能进行了研究。
Studied the promoter of the catalytic properties of iridium catalysts in hydroformylation of styrene by inorganic salts. 研究了无机盐对铱基催化剂在苯乙烯氢甲酰化反应中催化性能的改进。
The use of the water soluble rhodium phosphine complex for catalytic hydroformylation of dicyclopentadiene ( DCPD) in two phase system was studied. The effects of reaction temperature, phase transfer agent ( CTAB) and the concentration of rhodium catalyst were examined. 研究了采用水溶性铑膦络合催化体系对双环戊二烯的氢甲酰化反应,考查了反应温度、相转移剂CTAB、铑催化剂浓度等对反应的影响。
However, homogeneous catalysts are difficult to be recovered from hydroformylation products. 然而,匀相催化剂和产品的分离是困扰氢甲酰化工业生产的一大难题。
The reaction "pentanal synthesis via hydroformylation of 1-butene" is one of C4 resources comprehensive utilization effective ways. 1-丁烯氢甲酰化反应制戊醛是C4资源综合利用的有效途径之一。
There are many methods in synthesis of propionic acid in industry, such as hydroformylation of ethylene, carbonylation of ethanol. 工业上合成丙酸有乙烯氢甲酰化法、乙烯氢羰基化法和乙醇羰基化法等多种方法。