The results showed that during the chemical pretreatment the guaiacyl unit was more readily to be sulfonated and dissolved, and there were new conjugated carbonyl and quinoid structure formed. 结果表明,预处理过程中愈创木基易于磺化和溶出,木素中有新的共轭羰基和醌型结构产生。
Although aromatic rings were not changed very much, side chains of lignin such as carbonyl groups, CH2, syringic units and guaiacyl units were partly degraded. 对木质素的降解主要是存在于侧链上,虽然苯环骨架变化不明显,但木质素苯环间的羰基、CH2结构、紫丁香基和愈疮木基等侧链已部分被降解。
There were more carboxyl groups, condensed guaiacyl units and guaiacyl primary alcohol in the waste ASP liquor than those in KP waste liquor. 与KP相比,ASP废液中木素含有较多的羧基、缩合型愈创木基结构以及愈创木酚型的伯醇醚。
MWL of walnut shell belongs to guaiacyl-syringyl ( GS) lignin, but mainly guaiacyl lignin with the content of 80.68%; 核桃壳木质素属GS型木质素,其中G型木质素占多数,为80.68%;
Nm for n →π~ electron transition in UV spectra of the HBS lignin to indicate with a characteristic of unsaturated. According to the()~ 1H-NMR, there were many syringyl and guaiacyl groups in the peanut shell lignin. 从1H-NMR图谱中可知,花生壳HBS木质素存在明显的愈疮木基和紫丁香基苯环结构。
Judged from the()~ 1H NMR, the syringyl and guaiacyl group in the lignin is present. 从1HNMR图谱中看出存在明显的紫丁香基苯和愈疮木基环结构。
Guaiacyl and p-hydroxy phenyl structure of the lignin are the main positions for sand stabilization material synthesis cross-link reaction, and the reaction probability of guaiacyl and p-hydroxy phenyl structure in lignin is almost the same. 合成固沙材料的交联反应主要发生在木质素的愈创木基和对-羟基苯基结构上,并且愈创木基结构和对-羟基苯基结构发生交联反应的概率基本相同。