The review summarized the characteristics of~ 1H-NMR and~ ( 13) C-NMR spectra of two essential types of bisbenzylisoquinoline alkaloids ( BBI), berbamine series and bebeerine series ( head to head and tail to tail; head to tail and tail to head). 概括介绍了双苄基异喹啉类生物碱的两种基本类型berbamine系列和bebeerine系列(头接头与尾接尾;头接尾与尾接头)的~1H-NMR和~(13)C-NMR谱特征。